Recent experiments have reported the emergence of high-temperature superconductivity with critical temperature T-c between 43K and 123K in a potassium-doped aromatic hydrocarbon para-Terphenyl or p-Terphenyl. This achievement provides the record for the highest T-c in an organic superconductor overcoming the previous record of T-c = 38K in Cs3C60 fulleride. Here we propose that the driving mechanism is the quantum resonance between superconducting gaps near a Lifshitz transition which belongs to the class of Fano resonances called shape resonances. For the case of p-Terphenyl our numerical solutions of the multigap equation shows that high T-c is driven by tuning the chemical potential by K doping and it appears only in a narrow energy range near a Lifshitz transition. At the maximum critical temperature, T-c = 123 K, the condensate in the appearing new small Fermi surface pocket is in the BCS-BEC crossover while the T-c drops below 0.3K where it is in the BEC regime. Finally, we predict the experimental results which can support or falsify our proposed mechanism: a) the variation of the isotope coefficient as a function of the critical temperature and b) the variation of the gaps and their ratios 2 Delta/T-c as a function of T-c. Copyright (C) EPLA, 2017

Possible Fano resonance for high-T-c multi-gap superconductivity in p-Terphenyl doped by K at the Lifshitz transition

Valletta Antonio;Campi Gaetano;
2017

Abstract

Recent experiments have reported the emergence of high-temperature superconductivity with critical temperature T-c between 43K and 123K in a potassium-doped aromatic hydrocarbon para-Terphenyl or p-Terphenyl. This achievement provides the record for the highest T-c in an organic superconductor overcoming the previous record of T-c = 38K in Cs3C60 fulleride. Here we propose that the driving mechanism is the quantum resonance between superconducting gaps near a Lifshitz transition which belongs to the class of Fano resonances called shape resonances. For the case of p-Terphenyl our numerical solutions of the multigap equation shows that high T-c is driven by tuning the chemical potential by K doping and it appears only in a narrow energy range near a Lifshitz transition. At the maximum critical temperature, T-c = 123 K, the condensate in the appearing new small Fermi surface pocket is in the BCS-BEC crossover while the T-c drops below 0.3K where it is in the BEC regime. Finally, we predict the experimental results which can support or falsify our proposed mechanism: a) the variation of the isotope coefficient as a function of the critical temperature and b) the variation of the gaps and their ratios 2 Delta/T-c as a function of T-c. Copyright (C) EPLA, 2017
2017
Istituto di Cristallografia - IC
Istituto per la Microelettronica e Microsistemi - IMM
Inglese
118
3
37003-p1
37003-p7
7
https://doi.org/10.1209/0295-5075/118/37003
Sì, ma tipo non specificato
Organic superconductors
Theories and models of superconducting state
Occurrence
potential candidates
6
info:eu-repo/semantics/article
262
Mazziotti Maria, Vittoria; Valletta, Antonio; Campi, Gaetano; Innocenti, Davide; Perali, Andrea; Bianconi, Antonio
01 Contributo su Rivista::01.01 Articolo in rivista
none
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/20.500.14243/341250
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