Ultrahigh-temperature ZrB2-based ceramics with different sintering additions was developed for extreme conditions. Its strength characteristics, phase composition, and structure were examined. The ceramics was oxidized in air at 1250 and 1550°C. In addition, the most stable composites were subjected to temperature cycling in a flow of aviation fuel combustion products in a temperature range of 1400-1500°C. All materials show high oxidation resistance. The method used to produce samples influences their oxidation behavior: materials produced by vacuum hot pressing show higher oxidation resistance than those produced by hot pressing in a CO-CO2 atmosphere, probably because of their higher final density. The best results were obtained when ZrB2 sintering was combined with introduction of MoSi2 and CrB2

Ultrahigh-temperature ZrB2-based ceramics with different sintering additions was developed for extreme conditions. Its strength characteristics, phase composition, and structure were examined. The ceramics was oxidized in air at 1250 and 1550°C. In addition, the most stable composites were subjected to temperature cycling in a flow of aviation fuel combustion products in a temperature range of 1400-1500°C. All materials show high oxidation resistance. The method used to produce samples influences their oxidation behavior: materials produced by vacuum hot pressing show higher oxidation resistance than those produced by hot pressing in a CO-CO2 atmosphere, probably because of their higher final density. The best results were obtained when ZrB2 sintering was combined with introduction of MoSi2 and CrB2.

Behavior of ultra-high temperature ZrB2-based ceramics in oxidation

L Silvestroni
2018

Abstract

Ultrahigh-temperature ZrB2-based ceramics with different sintering additions was developed for extreme conditions. Its strength characteristics, phase composition, and structure were examined. The ceramics was oxidized in air at 1250 and 1550°C. In addition, the most stable composites were subjected to temperature cycling in a flow of aviation fuel combustion products in a temperature range of 1400-1500°C. All materials show high oxidation resistance. The method used to produce samples influences their oxidation behavior: materials produced by vacuum hot pressing show higher oxidation resistance than those produced by hot pressing in a CO-CO2 atmosphere, probably because of their higher final density. The best results were obtained when ZrB2 sintering was combined with introduction of MoSi2 and CrB2.
2018
Istituto di Scienza, Tecnologia e Sostenibilità per lo Sviluppo dei Materiali Ceramici - ISSMC (ex ISTEC)
Ultrahigh-temperature ZrB2-based ceramics with different sintering additions was developed for extreme conditions. Its strength characteristics, phase composition, and structure were examined. The ceramics was oxidized in air at 1250 and 1550°C. In addition, the most stable composites were subjected to temperature cycling in a flow of aviation fuel combustion products in a temperature range of 1400-1500°C. All materials show high oxidation resistance. The method used to produce samples influences their oxidation behavior: materials produced by vacuum hot pressing show higher oxidation resistance than those produced by hot pressing in a CO-CO2 atmosphere, probably because of their higher final density. The best results were obtained when ZrB2 sintering was combined with introduction of MoSi2 and CrB2
oxidation
ultrahigh-temperature ceramics
zirconium dibori
temperature cycling test.
File in questo prodotto:
Non ci sono file associati a questo prodotto.

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/20.500.14243/343692
Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus ND
  • ???jsp.display-item.citation.isi??? ND
social impact