Electrical control of nanoparticles arrays created via topological defect lines design in anisotropic fluids

Soft material templating is a promising approach for assembling and manipulating nanoparticles structures. Due to the high sensitivity of soft matter systems to external stimuli, such composite materials exploit the soft surrounding medium to move or to reconfigure nano-structures or nano-objects as well as to tune their own properties. The use of topological defects in anisotropic fluids has been recently reported. Here, arrays of defect lines are created in planar-periodic nematic liquid crystal cells, wherein the nematic director undergoes static twist deformations separated by topological defects. Trapping and manipulation of the nanoparticles in disclinations are demonstrated and investigated by confocal fluorescence microscopy exploiting quantum dots. Nanoparticles gathering is observed during electrically controlled switching from orientational topological walls to disclinations. The external field is also used to perform displacement and deformation of the nanoparticies arrays, as well as their dynamical assembling and disassembling. The reported results substantiate the opportunities offered by defects architectures in anisotropic fluids as a successful bottom-up approach that enables versatile assembling and remote control of nanoparticles. (C) 2017 Elsevier B.V. All rights reserved.