Thiazoles are intriguing heterocycles for the construction of Metal-Organic Frameworks (MOFs) and Coordination Polymers (CPs) of assorted dimensionality. Thiazoles and the related thiazolium salts are found in many natural products. Several compounds exhibit fluorescence properties and have been used for the preparation of organic light-emitting diodes (OLEDs) and semiconductor materials. A series of polymers with variable dimensionality spanning from 1D to 3D and featuring thiazole-based carboxylic acids as organic building blocks have been prepared and fully characterized in the solid state. Their performance as CO2 storage materials, as luminescent sensors for HgII in aqueous solutions or for luminescent water detection in halobenzenes has been scrutinized.
Thiazole-based Coordination Polymers and MOFs: Synthesis, Characterization and Applications in Luminescence and Gas Adsorption
Rossin Andrea;Tuci Giulia;Luconi Lapo;Giambastiani Giuliano;
2018
Abstract
Thiazoles are intriguing heterocycles for the construction of Metal-Organic Frameworks (MOFs) and Coordination Polymers (CPs) of assorted dimensionality. Thiazoles and the related thiazolium salts are found in many natural products. Several compounds exhibit fluorescence properties and have been used for the preparation of organic light-emitting diodes (OLEDs) and semiconductor materials. A series of polymers with variable dimensionality spanning from 1D to 3D and featuring thiazole-based carboxylic acids as organic building blocks have been prepared and fully characterized in the solid state. Their performance as CO2 storage materials, as luminescent sensors for HgII in aqueous solutions or for luminescent water detection in halobenzenes has been scrutinized.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
