Boride-based ceramics have strengths of 500-600 MPa up to 1500°C when doped with suitable secondary phases and densified using the proper sintering technique. However, in order for these materials to be employed in the ultra-high temperature regime, exploration of their performance at higher temperatures is necessary. Here, we present the strength behavior at temperatures up to 2100°C and show the effects of microstructure tailoring in terms of secondary phases, grain morphology and grain size. Strengths exceeding 1 GPa have been achieved at 1800°C and analysis showed this behavior was due to sub-grain refinement which occurred as a consequence of intragranular plasticity under load.

Boride ceramics with high strength at ultra-high temperatures

Laura Silvestroni;
2018

Abstract

Boride-based ceramics have strengths of 500-600 MPa up to 1500°C when doped with suitable secondary phases and densified using the proper sintering technique. However, in order for these materials to be employed in the ultra-high temperature regime, exploration of their performance at higher temperatures is necessary. Here, we present the strength behavior at temperatures up to 2100°C and show the effects of microstructure tailoring in terms of secondary phases, grain morphology and grain size. Strengths exceeding 1 GPa have been achieved at 1800°C and analysis showed this behavior was due to sub-grain refinement which occurred as a consequence of intragranular plasticity under load.
2018
Istituto di Scienza, Tecnologia e Sostenibilità per lo Sviluppo dei Materiali Ceramici - ISSMC (ex ISTEC)
UHTC
W-doping
HT strength
core-shell
alloying
annealing
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/20.500.14243/344957
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