We have also investigated the Second Harmonic Generation (SHG) of composite films based on the various cyclometallated Ir(III) complexes dispersed and oriented in a polymethylmethacrylate (PMMA) matrix. (c) 2013 Elsevier B.V. All rights reserved.
We studied the second-order NLO properties in solution of various Ir(III) acetylacetonate complexes bearing a substituted cyclometallated 4-styryl-2-phenylpyridine (ppy-4-styryl-R, with R = NEt2, OMe, H, NO2) with the EFISH technique. The dipole moments were evaluated by Density Functional Theory (DFT) calculations.
Functionalized styryl iridium(III) complexes as active second-order NLO chromophores and building blocks for SHG polymeric films
Marinotto Daniele;Valore Adriana;
2014
Abstract
We studied the second-order NLO properties in solution of various Ir(III) acetylacetonate complexes bearing a substituted cyclometallated 4-styryl-2-phenylpyridine (ppy-4-styryl-R, with R = NEt2, OMe, H, NO2) with the EFISH technique. The dipole moments were evaluated by Density Functional Theory (DFT) calculations.File in questo prodotto:
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