This work reports a high power, stable, completely Pt-free anion exchange membrane fuel cell (AEMFC) comprised of highly active catalysts - Pd-CeO2/C at the anode and PdCu/C alloy at the cathode for the hydrogen oxidation and oxygen reduction reactions, respectively. The resulting AEMFC shows outstanding performance, reaching a peak power density of 1 W cm(-2), twice the value of the best performance for Pt-free cells reported in the literature to date. The AEMFC also shows a low voltage degradation rate when operated continuously for more than 100 h at a constant 0.5 A cm(2), with a voltage degradation rate of only 2.5 mV h(-1), which is excellent when compared to nearly all of the AEMFCs reported in the literature to date. This combination of high performance and high stability in the absence of Pt-based catalysts represents a significant landmark in the progress of the AEMFC technology. (C) The Author(s) 2018. Published by ECS.

Beyond 1.0 W cm(-2) Performance without Platinum: The Beginning of a New Era in Anion Exchange Membrane Fuel Cells

Miller Hamish A;Vizza Francesco;
2018

Abstract

This work reports a high power, stable, completely Pt-free anion exchange membrane fuel cell (AEMFC) comprised of highly active catalysts - Pd-CeO2/C at the anode and PdCu/C alloy at the cathode for the hydrogen oxidation and oxygen reduction reactions, respectively. The resulting AEMFC shows outstanding performance, reaching a peak power density of 1 W cm(-2), twice the value of the best performance for Pt-free cells reported in the literature to date. The AEMFC also shows a low voltage degradation rate when operated continuously for more than 100 h at a constant 0.5 A cm(2), with a voltage degradation rate of only 2.5 mV h(-1), which is excellent when compared to nearly all of the AEMFCs reported in the literature to date. This combination of high performance and high stability in the absence of Pt-based catalysts represents a significant landmark in the progress of the AEMFC technology. (C) The Author(s) 2018. Published by ECS.
2018
Istituto di Chimica dei Composti OrganoMetallici - ICCOM -
Fuel cells
anion exchange membrane
platinum free
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/20.500.14243/346547
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