This work reports a high power, stable, completely Pt-free anion exchange membrane fuel cell (AEMFC) comprised of highly active catalysts - Pd-CeO2/C at the anode and PdCu/C alloy at the cathode for the hydrogen oxidation and oxygen reduction reactions, respectively. The resulting AEMFC shows outstanding performance, reaching a peak power density of 1 W cm(-2), twice the value of the best performance for Pt-free cells reported in the literature to date. The AEMFC also shows a low voltage degradation rate when operated continuously for more than 100 h at a constant 0.5 A cm(2), with a voltage degradation rate of only 2.5 mV h(-1), which is excellent when compared to nearly all of the AEMFCs reported in the literature to date. This combination of high performance and high stability in the absence of Pt-based catalysts represents a significant landmark in the progress of the AEMFC technology. (C) The Author(s) 2018. Published by ECS.

Beyond 1.0 W cm(-2) Performance without Platinum: The Beginning of a New Era in Anion Exchange Membrane Fuel Cells

Miller Hamish A;Vizza Francesco;
2018

Abstract

This work reports a high power, stable, completely Pt-free anion exchange membrane fuel cell (AEMFC) comprised of highly active catalysts - Pd-CeO2/C at the anode and PdCu/C alloy at the cathode for the hydrogen oxidation and oxygen reduction reactions, respectively. The resulting AEMFC shows outstanding performance, reaching a peak power density of 1 W cm(-2), twice the value of the best performance for Pt-free cells reported in the literature to date. The AEMFC also shows a low voltage degradation rate when operated continuously for more than 100 h at a constant 0.5 A cm(2), with a voltage degradation rate of only 2.5 mV h(-1), which is excellent when compared to nearly all of the AEMFCs reported in the literature to date. This combination of high performance and high stability in the absence of Pt-based catalysts represents a significant landmark in the progress of the AEMFC technology. (C) The Author(s) 2018. Published by ECS.
2018
Istituto di Chimica dei Composti OrganoMetallici - ICCOM -
Inglese
165
15
J3039
J3044
6
https://iopscience.iop.org/article/10.1149/2.0071815jes
Sì, ma tipo non specificato
Fuel cells
anion exchange membrane
platinum free
1
8
info:eu-repo/semantics/article
262
Omasta Travis, J; Peng, Xiong; Miller Hamish, A; Vizza, Francesco; Wang, Lianqin; Varcoe John, R; Dekel Dario, R; Mustain William, E
01 Contributo su Rivista::01.01 Articolo in rivista
none
File in questo prodotto:
Non ci sono file associati a questo prodotto.

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/20.500.14243/346547
Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 103
  • ???jsp.display-item.citation.isi??? 98
social impact