High yields of valued benzaldehyde and benzyl benzoate are obtained in one pot starting from benzyl alcohol using oxygen as only oxidant under mild conditions (2 bar O2, 100 °C) along with an ultralow amount (0.02 mol %) of Au nanoparticles heterogenized over a spherical ORMOSIL mesoporous support. The process is remarkably selective and the catalyst is stable.

Green and Direct Synthesis of Benzaldehyde and Benzyl Benzoate in One Pot

Ciriminna Rosaria;La Parola Valeria;Giordano Francesco;Pagliaro Mario
2018

Abstract

High yields of valued benzaldehyde and benzyl benzoate are obtained in one pot starting from benzyl alcohol using oxygen as only oxidant under mild conditions (2 bar O2, 100 °C) along with an ultralow amount (0.02 mol %) of Au nanoparticles heterogenized over a spherical ORMOSIL mesoporous support. The process is remarkably selective and the catalyst is stable.
2018
Istituto per lo Studio dei Materiali Nanostrutturati - ISMN
Aerobic oxidation
Benzaldehyde
Benzyl benzoate
Gold catalysis
One pot
ORMOSIL
Solagel catalysis
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/20.500.14243/347535
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