This work describes a straightforward approach to the production of highly-performing and costeffective C-based materials for energy storage application while proposing an original and effective method to the control of the final material morphology. Indeed, robust few-layer graphene-like and highly open-cell structures have been prepared by a modified chemical activation procedure starting from costless sugar/salt mixtures. The as-prepared C-samples ensure high ion-accessible surface area and low ion transport resistance, two key features for the fabrication of effective electrochemical double layer supercapacitors. A selected sample from this series exhibits high specific capacitance (Cg) (312 and 234 F g-1 at 0.5 and 50 A g-1 , respectively, in 0.5 M H2SO4), particularly at high current density values, along with excellent cycling stability and Cg retention for increasing chargeedischarge rates.

Tridimensional few-layer graphene-like structures from sugar-salt mixtures as high-performance supercapacitor electrodes

Tuci Giulia;Giambastiani Giuliano;
2018

Abstract

This work describes a straightforward approach to the production of highly-performing and costeffective C-based materials for energy storage application while proposing an original and effective method to the control of the final material morphology. Indeed, robust few-layer graphene-like and highly open-cell structures have been prepared by a modified chemical activation procedure starting from costless sugar/salt mixtures. The as-prepared C-samples ensure high ion-accessible surface area and low ion transport resistance, two key features for the fabrication of effective electrochemical double layer supercapacitors. A selected sample from this series exhibits high specific capacitance (Cg) (312 and 234 F g-1 at 0.5 and 50 A g-1 , respectively, in 0.5 M H2SO4), particularly at high current density values, along with excellent cycling stability and Cg retention for increasing chargeedischarge rates.
2018
Istituto di Chimica dei Composti OrganoMetallici - ICCOM -
3D graphene-like materials
Salt templating method
Chemical activation
Natural C-sources
Supercapacitors
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/20.500.14243/348740
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