Gold nanarods (GNRs) with an aspect ratio equal to 3:1 and 4:1 and a major axis equal to 50 nm, silanized and capped with titania (c-GNRs), were embedded within the 6 µ thick semiconductor layer of DSSCs based on an organic D-?-A sensitizer dye (L0 or L1) and a squaraine co-sensitizer (SQ2). These dye cocktails and a transparent titania paste were selected to maximize the transmittance of DSSCs in a region of maximum visual acuity. Absorbance, transmittance and reflectance spectra of the films were measured after they were dyed. The plasmonic effects were distinguishable both in absorbance and absorptance spectra for all the types of cocktails of dyes and GNRs aspect ratios used.
The role of silanized and capped with TiO2 gold nanorods of different aspect ratios in co-sensitized DSSCs for transparent windows applications
Marina Mazzoni;Lorenzo Zani;Sarah Lai;Sonia Centi;Roberto Pini;Fulvio Ratto
2018
Abstract
Gold nanarods (GNRs) with an aspect ratio equal to 3:1 and 4:1 and a major axis equal to 50 nm, silanized and capped with titania (c-GNRs), were embedded within the 6 µ thick semiconductor layer of DSSCs based on an organic D-?-A sensitizer dye (L0 or L1) and a squaraine co-sensitizer (SQ2). These dye cocktails and a transparent titania paste were selected to maximize the transmittance of DSSCs in a region of maximum visual acuity. Absorbance, transmittance and reflectance spectra of the films were measured after they were dyed. The plasmonic effects were distinguishable both in absorbance and absorptance spectra for all the types of cocktails of dyes and GNRs aspect ratios used.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
