New oligophenylenevinylene-terminated phenylenevinylene dendrons have been prepared and attached to C-60 by a 1,3-dipolar cycloaddition of the azomethine ylides generated in situ from the dendritic aldehydes and N-methylglycine. Preliminary photophysical investigations of the resulting fullerodendrimers have revealed interesting light-harvesting properties.
Functionalization of [60]fullerene with New Light-Collecting Oligophenylenevinylene-Terminated Dendritic Wedges
Accorsi G;Armaroli N;
2002
Abstract
New oligophenylenevinylene-terminated phenylenevinylene dendrons have been prepared and attached to C-60 by a 1,3-dipolar cycloaddition of the azomethine ylides generated in situ from the dendritic aldehydes and N-methylglycine. Preliminary photophysical investigations of the resulting fullerodendrimers have revealed interesting light-harvesting properties.File in questo prodotto:
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