Preliminary assessment of the quality of Methyl chloride (CH3Cl) from MIPAS on ENVISAT measurements

The Michelson Interferometer for Passive Atmospheric Sounding (MIPAS) is a limb-viewing infrared Fourier transform spectrometer that operated from 2002 to 2012 on board the ENVISAT satellite. The fruitful collaboration among spectroscopists, Level 1, Level 2, and validation teams in the frame of the MIPAS Quality Working Group has recently led to the implementation of significant changes in both ESA Level 1 and Level 2 processors, as well as in the spectroscopic database and in some absorption cross-sections. In addition to the products already present in V7 dataset (temperature and the VMR of H2O, O3, HNO3, CH4, N2O, NO2, CFC-11, CFC-12, N2O5, ClONO2, HCFC-22, COF2, CF4, HCN and CCl4), the VMR of six additional species (OCS, CH3Cl, HDO, C2H2, C2H6, COCl2) will be provided in V8 dataset.Among the new species, methyl chloride (CH3Cl) is of great interest in stratospheric ozone chemistry since it is the most abundant chlorine-containing gas in the troposphere and, in contrast to other relatively long-lived ozone-depleting gases, it has both natural and anthropogenic sources, with the known emission being mainly natural (tropical plants, biomass burning, the ocean, salt marshes and fungi). Since it is not controlled under the Montreal Protocol, its importance is expected to increase in the coming decades as emission controls alter the relative contributions from natural and anthropogenic halogen sources.In this paper we present a preliminary assessment of the quality of the MIPAS CH3Cl data, in terms of precision, accuracy and vertical resolution, and we investigate the spatial and seasonal variations in the distribution of CH3Cl in the upper troposphere/lower stratosphere (UTLS).