We present gain and lasing results from a polyrotaxane consisting of a conjugated polymer (polyfluorene-alt-biphenylene) threaded through sugar macrocycles (beta-cyclodextrin). Encapsulation suppresses interchain charge separation, leading to lasing emission not observed in the unthreaded polymer, and enlargement of the stimulated emission in threaded polymer is observed. We demonstrate all-optical switching distributed feedback laser.
Laser action from a sugar-threaded polyrotaxane
T Virgili;G Gigli;
2009
Abstract
We present gain and lasing results from a polyrotaxane consisting of a conjugated polymer (polyfluorene-alt-biphenylene) threaded through sugar macrocycles (beta-cyclodextrin). Encapsulation suppresses interchain charge separation, leading to lasing emission not observed in the unthreaded polymer, and enlargement of the stimulated emission in threaded polymer is observed. We demonstrate all-optical switching distributed feedback laser.File in questo prodotto:
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