The demand for high dielectric constant materials and high energy density capacitors has rapidly increased in recent years due to the continuous and rapid development of the electronic industry and the need to store electrostatic energy more efficiently. The high breakdown field typical of polymers can be preserved while increasing the effective permittivity, if ferroelectric inclusions are embedded in the polymer matrix by forming a 0-3 connectivity composite, thus improving the stored energy density. The dielectric properties of the composite can be tailored by varying size, shape and volume fraction of the inclusions as well as the dielectric constant of the polymeric matrix, thus altering the electric field distribution inside the material. Moreover, the distribution of the electric field can be modified by coating the particles used as inclusions with an oxide layer with a different dielectric constant. In this work we have fabricated poly(vinylidene fluoride) (PVDF) composites containing 30 vol.% BaTiO3@AO2 (A = Si, Ti) particles and measured their dielectric properties. Barium titanate particles with a diameter of ?100 nm were synthesized using a hydrothermal-like method and coated with a thin shell (?10 nm) of SiO2 or TiO2 by means of colloidal chemistry methods. The composites were prepared by solvent casting followed by compression moulding. The dielectric properties of the composites (permittivity and loss tangent) were measured at different frequencies and several temperatures. The coating results in a significant modification of the effective permittivity, which is mainly determined by the value of its dielectric constant. To gain insight into the role of the coating layer, the electric field distribution and effective dielectric constant were calculated for the different composites using a 3D finite element modelling and compared to experimental results. Acknowledgement Work carried out in the framework of Project Polycom (IDROL:10359) funded by Fondazione Bancaria Compagnia di San Paolo.
Engineered ferroelectric PVDF composites containing BaTiO3-based core-shell inclusions: dielectric properties and 3D FEM modelling of field distribution
Canu G;Brunengo E;Buscaglia MT;Conzatti L;Costa C;Schizzi I;Buscaglia V;Stagnaro P
2018
Abstract
The demand for high dielectric constant materials and high energy density capacitors has rapidly increased in recent years due to the continuous and rapid development of the electronic industry and the need to store electrostatic energy more efficiently. The high breakdown field typical of polymers can be preserved while increasing the effective permittivity, if ferroelectric inclusions are embedded in the polymer matrix by forming a 0-3 connectivity composite, thus improving the stored energy density. The dielectric properties of the composite can be tailored by varying size, shape and volume fraction of the inclusions as well as the dielectric constant of the polymeric matrix, thus altering the electric field distribution inside the material. Moreover, the distribution of the electric field can be modified by coating the particles used as inclusions with an oxide layer with a different dielectric constant. In this work we have fabricated poly(vinylidene fluoride) (PVDF) composites containing 30 vol.% BaTiO3@AO2 (A = Si, Ti) particles and measured their dielectric properties. Barium titanate particles with a diameter of ?100 nm were synthesized using a hydrothermal-like method and coated with a thin shell (?10 nm) of SiO2 or TiO2 by means of colloidal chemistry methods. The composites were prepared by solvent casting followed by compression moulding. The dielectric properties of the composites (permittivity and loss tangent) were measured at different frequencies and several temperatures. The coating results in a significant modification of the effective permittivity, which is mainly determined by the value of its dielectric constant. To gain insight into the role of the coating layer, the electric field distribution and effective dielectric constant were calculated for the different composites using a 3D finite element modelling and compared to experimental results. Acknowledgement Work carried out in the framework of Project Polycom (IDROL:10359) funded by Fondazione Bancaria Compagnia di San Paolo.File | Dimensione | Formato | |
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