A bimetallic titanium(salen) complex has been used to catalyze the asymmetric addition of potassium cyanide to aldehydes attached to Wang resin giving polymer supported cyanohydrin propionates with up to 91% enantiomeric excesses. (c) 2005 Elsevier Ltd. All rights reserved.
Asymmetric synthesis of polymer-supported cyanohydrin acetates
Carta P;
2005
Abstract
A bimetallic titanium(salen) complex has been used to catalyze the asymmetric addition of potassium cyanide to aldehydes attached to Wang resin giving polymer supported cyanohydrin propionates with up to 91% enantiomeric excesses. (c) 2005 Elsevier Ltd. All rights reserved.File in questo prodotto:
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