Recent advances in developing high-performance anion exchange membranes (AEMs) for fuel cell (AEMFC) applications enable catalyst developers to investigate and test cheaper and/or more sustainable materials under operando fuel cell conditions. In this article, we integrate a high-performance Pd-CeO2/C hydrogen oxidation reaction (HOR) catalyst into AEMFCs in combination with different Pt and Pt-free cathodes. A H2/O2 AEMFC peak power performance of 2 W cm-2 at 80 °C is obtained when using a Pt/C cathode (2 A cm-2 is achieved at a cell voltage of 0.6 V), which translates to 1 W cm-2 peak power density (0.7 A cm-2 is achieved at 0.6 V) at 60 °C with the switch to a cheap, critical raw material (CRM)-free Fe/C cathode catalyst.
Integration of a Pd-CeO2/C Anode with Pt and Pt-Free Cathode Catalysts in High Power Density Anion Exchange Membrane Fuel Cells
Hamish A. Miller;Maria V. Pagliaro;Marco Bellini;Francesco Bartoli;Francesco Vizza
2020
Abstract
Recent advances in developing high-performance anion exchange membranes (AEMs) for fuel cell (AEMFC) applications enable catalyst developers to investigate and test cheaper and/or more sustainable materials under operando fuel cell conditions. In this article, we integrate a high-performance Pd-CeO2/C hydrogen oxidation reaction (HOR) catalyst into AEMFCs in combination with different Pt and Pt-free cathodes. A H2/O2 AEMFC peak power performance of 2 W cm-2 at 80 °C is obtained when using a Pt/C cathode (2 A cm-2 is achieved at a cell voltage of 0.6 V), which translates to 1 W cm-2 peak power density (0.7 A cm-2 is achieved at 0.6 V) at 60 °C with the switch to a cheap, critical raw material (CRM)-free Fe/C cathode catalyst.File | Dimensione | Formato | |
---|---|---|---|
ACS Appl. Energy Mater. 2020, 3, 10, 10209–10214.pdf
solo utenti autorizzati
Tipologia:
Versione Editoriale (PDF)
Licenza:
NON PUBBLICO - Accesso privato/ristretto
Dimensione
1.27 MB
Formato
Adobe PDF
|
1.27 MB | Adobe PDF | Visualizza/Apri Richiedi una copia |
High power density Anion Exchange Membrane Fuel cells with Pd-CeO2-C anode and Pt-free cathode catalysts (AAM).pdf
Open Access dal 14/10/2021
Descrizione: “This document is the Accepted Manuscript version of a Published Work that appeared in final form in ACS Applied Energy Materials, copyright © 2020 American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acsaem.0c01998."
Tipologia:
Documento in Post-print
Licenza:
Altro tipo di licenza
Dimensione
959 kB
Formato
Adobe PDF
|
959 kB | Adobe PDF | Visualizza/Apri |
ae0c01998_si_001.pdf
accesso aperto
Descrizione: supporting information
Tipologia:
Altro materiale allegato
Licenza:
Altro tipo di licenza
Dimensione
306.55 kB
Formato
Adobe PDF
|
306.55 kB | Adobe PDF | Visualizza/Apri |
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.