The O 1s" border=0 src="http://ojps.aip.org/stockgif2/rarr.gif"* transition below the O K-edge in O2 has been investigated by absorption, constant ionic state (CIS) experiments, and extensive configuration interaction calculations. CIS scans of the three lowest-lying final states reached in resonant Auger decay provide a wealth of information on energy range, symmetry, and spin multiplicity of the intermediate states with * character. We conclude that the identification of only two exchange-split components is inadequate because a complex manifold of states with * character exists with no unique energy difference between related states.
The O 1s.s* Resonance in O2: exchange splitting revisited
Carravetta V;
2002
Abstract
The O 1s" border=0 src="http://ojps.aip.org/stockgif2/rarr.gif"* transition below the O K-edge in O2 has been investigated by absorption, constant ionic state (CIS) experiments, and extensive configuration interaction calculations. CIS scans of the three lowest-lying final states reached in resonant Auger decay provide a wealth of information on energy range, symmetry, and spin multiplicity of the intermediate states with * character. We conclude that the identification of only two exchange-split components is inadequate because a complex manifold of states with * character exists with no unique energy difference between related states.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
