Time resolved data unveils the complex DOM dynamics in a Mediterranean river

In this study, dissolved organic carbon (DOC) data and optical properties (absorbance and fluorescence) of DOM, weekly collected in the Arno River for 2 years, are used to investigate the main processes determining DOM temporal dynamics in a small Mediterranean river, with torrential hydrology and medium-high human impact, and to quantify the contribution of this river to Med Sea carbon budget. A clear seasonal cycle of DOM, with DOC values ranging between 170 and 490 ?M, was observed. Optical properties indicates that DOM quality in the river is different depending on the season; terrestrial humic-like substances prevail in winter, when discharge and floods are the main drivers of DOM concentration and quality, whereas autochthonous protein-like substances prevail in spring and summer, when biological processes dominate. Our results provide a robust estimate of the DOC flux to the Med Sea (9.6 · 109 g DOC yr-1) and of its range of variability (12.95 · 109-5.12 · 109 g DOC yr-1). The 80% of this flux was generally delivered during autumn/winter with significant amounts ascribed to single flood events (up to 26% in 2014). This study, by providing a rich dataset on water quantity and quality and by quantifying the importance of the hydrological regime on DOC transport, represents an important step toward a quantitative modeling of the Arno River.