Interpolation formulas are presented to reproduce the rate coefficients for vibrational-translational energy exchange and dissociation for the N + N-2 collision process. The original data have been obtained by quasiclassical method in a detailed way, including the effect of molecular rotation. The fitting procedure results are compared with original data and the related error is evaluated. Comparison with global experimental dissociation results is also presented.
N-N2 state to state vibrational-relaxation and dissociation rates based on quasiclassical calculations
F Esposito;I Armenise;
2006
Abstract
Interpolation formulas are presented to reproduce the rate coefficients for vibrational-translational energy exchange and dissociation for the N + N-2 collision process. The original data have been obtained by quasiclassical method in a detailed way, including the effect of molecular rotation. The fitting procedure results are compared with original data and the related error is evaluated. Comparison with global experimental dissociation results is also presented.File in questo prodotto:
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Descrizione: N-N2 vibrational relaxation rates
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