The CO2 uptake by single 2-amino-2-methyl-1-propanol (AMP) and its blends with 2-(ethylamino)ethanol (EMEA) or N-methyl-2,2?-iminodiethanol (MDEA) has been investigated in both aqueous and nonaqueous solutions, and compared with aqueous 2-aminoethanol (MEA), the most used sorbent in carbon capture and storage (CCS) processes. The loading capacity, the rate of absorption, and the heat of CO2 absorption have been experimentally determined for all the amine solutions. 13C NMR analysis allowed the identification of the carbonated species formed in solution and evaluation of their relative amounts. The most promising sorbents have been further tested in continuous cycles of absorption and desorption carried out in packed columns, in order to verify their CO2 (15% in N2) capture efficiency. Thanks to their good CO2 loading, high rate of reaction with CO2, and low heat of absorption, the AMP-EMEA blend solutions, both in water and in organic diluents, are good candidates for CO2 capture as an alternative to the conventional aqueous MEA solution.
Comparative Study of CO 2 Capture by Aqueous and Nonaqueous 2-Amino-2-methyl-1-propanol Based Absorbents Carried Out by 13 C NMR and Enthalpy Analysis
Barzagli F;Peruzzini M
2019
Abstract
The CO2 uptake by single 2-amino-2-methyl-1-propanol (AMP) and its blends with 2-(ethylamino)ethanol (EMEA) or N-methyl-2,2?-iminodiethanol (MDEA) has been investigated in both aqueous and nonaqueous solutions, and compared with aqueous 2-aminoethanol (MEA), the most used sorbent in carbon capture and storage (CCS) processes. The loading capacity, the rate of absorption, and the heat of CO2 absorption have been experimentally determined for all the amine solutions. 13C NMR analysis allowed the identification of the carbonated species formed in solution and evaluation of their relative amounts. The most promising sorbents have been further tested in continuous cycles of absorption and desorption carried out in packed columns, in order to verify their CO2 (15% in N2) capture efficiency. Thanks to their good CO2 loading, high rate of reaction with CO2, and low heat of absorption, the AMP-EMEA blend solutions, both in water and in organic diluents, are good candidates for CO2 capture as an alternative to the conventional aqueous MEA solution.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
