Silver terbium diphosphate AgTbP2O7 was prepared by solid state reaction at T=500° and characterized by combining SEM-EDS morphological investigation and semi-quantitative chemi-cal analysis via Scanning Electron Microscopy (SEM) equipped with energy dispersive X-Ray spectroscopy (EDS), structure solution via Rietveld refinement of powder X-ray diffraction (PXRD) data, and Fourier transform infrared (FTIR) spectros-copy. The synthesized compound is monoclinic, P21/n space group, with cell parameters: a = 11.9108(3) Å, b = 6.90265(16) Å, c = 6.62030(15) Å, ? = 90.3702(5)° and V=544.28(2) Å3. The crystal structure consists of a network of zig-zag chains of TbO8 polyhedra extending along the b axis, bridged by P2O7 diphosphate groups and by chains of AgO7 polyhedra running along the c crystallographic direction. MIR (medium infrared) spectrum shows bands typical of P-O modes of diphosphate compounds. Observed band multiplicity is in agreement with the symmetry reduction with respect to orthorhombic rare earth diphosphates with similar stoichiometries reported in the litera-ture.
Preparation, structural and spectroscopical properties of silver terbium diphosphate AgTbP 2 O 7
Rizzi Rosanna;Capitelli Francesco;Corriero Nicola;Altomare Angela
2019
Abstract
Silver terbium diphosphate AgTbP2O7 was prepared by solid state reaction at T=500° and characterized by combining SEM-EDS morphological investigation and semi-quantitative chemi-cal analysis via Scanning Electron Microscopy (SEM) equipped with energy dispersive X-Ray spectroscopy (EDS), structure solution via Rietveld refinement of powder X-ray diffraction (PXRD) data, and Fourier transform infrared (FTIR) spectros-copy. The synthesized compound is monoclinic, P21/n space group, with cell parameters: a = 11.9108(3) Å, b = 6.90265(16) Å, c = 6.62030(15) Å, ? = 90.3702(5)° and V=544.28(2) Å3. The crystal structure consists of a network of zig-zag chains of TbO8 polyhedra extending along the b axis, bridged by P2O7 diphosphate groups and by chains of AgO7 polyhedra running along the c crystallographic direction. MIR (medium infrared) spectrum shows bands typical of P-O modes of diphosphate compounds. Observed band multiplicity is in agreement with the symmetry reduction with respect to orthorhombic rare earth diphosphates with similar stoichiometries reported in the litera-ture.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
