Due to rapid population growth and intensification of agricultural and industrial activities, a diverse array of hazardous pollutants is progressively entered in the aquatic system. Particularly, persistent organic contaminants such as pesticides, solvents, dyes, detergents and industrial chemicals, constitute a pressing ecological problem that poses a great threat to human health [1]. An eco-friendly and definitive process to eliminate contaminants from water is concerned on their complete mineralization by using photocatalytic approach [2], followed by an efficient and easily catalyst separation at the end of the process. In light of this, we have formulated a novel multifunctional super-adsorbent sponge based on poly-2-hydroxyethyl methacrylate/graphene oxide (pHEMA@GO) composite developed by a cryo-polymerization in water [3]. In addition, taking advantages by the hydroxyl pendant groups present on both HEMA and GO moieties, our strategy involves the use of the sponge as a platform to link covalently ZnO by using Atomic Layer Deposition (ALD). This step can provide them the ability to degrade pollutants via photocatalytic process after the adsorption.
ZnO-PHEMA@GO NANOCOMPOSITES: AN ENVIRONMENTAL SUSTAINABLE MATERIAL FOR WATER TREATMENT
Martina Ussia;Alessandro Di Mauro;Tommaso Mecca;Francesca Cunsolo;Pierfrancesco Cerruti;Vittorio Privitera;Sabrina C Carroccio
2019
Abstract
Due to rapid population growth and intensification of agricultural and industrial activities, a diverse array of hazardous pollutants is progressively entered in the aquatic system. Particularly, persistent organic contaminants such as pesticides, solvents, dyes, detergents and industrial chemicals, constitute a pressing ecological problem that poses a great threat to human health [1]. An eco-friendly and definitive process to eliminate contaminants from water is concerned on their complete mineralization by using photocatalytic approach [2], followed by an efficient and easily catalyst separation at the end of the process. In light of this, we have formulated a novel multifunctional super-adsorbent sponge based on poly-2-hydroxyethyl methacrylate/graphene oxide (pHEMA@GO) composite developed by a cryo-polymerization in water [3]. In addition, taking advantages by the hydroxyl pendant groups present on both HEMA and GO moieties, our strategy involves the use of the sponge as a platform to link covalently ZnO by using Atomic Layer Deposition (ALD). This step can provide them the ability to degrade pollutants via photocatalytic process after the adsorption.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.