Acid catalysis is widely used in the chemical industry, and nowadays many efforts are being focused on replacing the more common homogeneous catalysts with heterogeneous ones in order to make greener the industrial processes. In this perspective, sulfonic solid acid materials rep-resent a valid alternative to the homogenous mineral acid in several acid catalyzed reactions. In this minireview, an overview of the recent advances on the preparation, stability and application of these materials is reported. Special attention is addressed to the sustainability of the considered processes, starting from the catalyst's preparation, the use of green solvents and reducing the possible reaction steps. Ways to tackle the main drawback represented by easy leaching of acid groups are described. For an easy catalyst recovery, the use of a magnetic core in a catalyst particle, with the related synthetic approaches, is also illustrated. Finally, a section is dedicated to the principal characterization techniques to identify the structural properties of the catalysts.

Sulfonic acid-functionalized inorganic materials as efficient catalysts in various applications: A minireview

Testa Maria Luisa
Primo
;
La Parola Valeria
Ultimo
2021

Abstract

Acid catalysis is widely used in the chemical industry, and nowadays many efforts are being focused on replacing the more common homogeneous catalysts with heterogeneous ones in order to make greener the industrial processes. In this perspective, sulfonic solid acid materials rep-resent a valid alternative to the homogenous mineral acid in several acid catalyzed reactions. In this minireview, an overview of the recent advances on the preparation, stability and application of these materials is reported. Special attention is addressed to the sustainability of the considered processes, starting from the catalyst's preparation, the use of green solvents and reducing the possible reaction steps. Ways to tackle the main drawback represented by easy leaching of acid groups are described. For an easy catalyst recovery, the use of a magnetic core in a catalyst particle, with the related synthetic approaches, is also illustrated. Finally, a section is dedicated to the principal characterization techniques to identify the structural properties of the catalysts.
2021
Istituto per lo Studio dei Materiali Nanostrutturati - ISMN
Metal oxide support
Sulfonic acid catalysts
Sulfonic characterization techniques
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Descrizione: Sulfonic acid-functionalized inorganic materials as efficient catalysts in various applications: A minireview
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/20.500.14243/396655
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