The goal is to investigate the feasibility to use a local biomass (Posidonia Oceanica and Wood chips), as a raw precursor, to the production of activated carbons (AC) with a high surface area and remarkable hydrogen (H) adsorption properties. Biomasses (particle size of 0.3-0.4 mm) were pyrolyzed at 600 °C with a heating rate of 5 °C/min under an argon atmosphere. The biochar obtained from the carbonization step was chemically activated with KOH. The activation methodology induces a considerable improvement of the properties of the porous carbon in terms of carbon content (from 58 to 69 wt% to 93-96 wt%), surface area (from 41 to 425 m/g to 2810-2835 m/g) and H adsorption in cryogenic condition (from 0,1 wt% to over 5 wt%). All porous carbons were characterized in terms of elemental analysis (CHNS-O), textural properties and H adsorption measurements.
Posidonia Oceanica and Wood chips activated carbon as interesting materials for hydrogen storage
Pedicini RPrimo
Writing – Review & Editing
;Maisano S;Chiodo V;
2020
Abstract
The goal is to investigate the feasibility to use a local biomass (Posidonia Oceanica and Wood chips), as a raw precursor, to the production of activated carbons (AC) with a high surface area and remarkable hydrogen (H) adsorption properties. Biomasses (particle size of 0.3-0.4 mm) were pyrolyzed at 600 °C with a heating rate of 5 °C/min under an argon atmosphere. The biochar obtained from the carbonization step was chemically activated with KOH. The activation methodology induces a considerable improvement of the properties of the porous carbon in terms of carbon content (from 58 to 69 wt% to 93-96 wt%), surface area (from 41 to 425 m/g to 2810-2835 m/g) and H adsorption in cryogenic condition (from 0,1 wt% to over 5 wt%). All porous carbons were characterized in terms of elemental analysis (CHNS-O), textural properties and H adsorption measurements.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.