A series of dioxidomolybdenum(VI) complexes, [MoOL] (1-6) and [MoOL(solv)] (1a-6a) {where solv (solvent) = DMSO (1a, 3a, 5a and 6a) and HO (2a and 4a)} have been synthesized using thiosemicarbazone ligands, HL. Furthermore, six monooxidomolybdenum(IV) complexes [MoOL(N-N)] (7-12) {where co-ligand (N-N) = 2,2?-bipyridine (bipy) (7, 10 and 11) and 1,10-phenanthroline (phen) (8, 9 and 12)} have also been synthesized from the corresponding Mo(VI) precursors, [MoOL] (1-6) by oxygen atom transfer (OAT) reaction. Complexes have been characterized by conventional methods, including X-ray crystallography, and DFT (density functional theory) calculations. OAT reactivity of Mo(VI) and Mo(IV) complexes have been successfully established through the formation of OPPh and MeS. These OAT products have been characterized by P NMR (OPPh), UV-Vis spectroscopy and GC-MS (MeS) and DFT simulations supported this finding through the prediction of ?G for the reaction of oxygen atom transfer. DFT methods suggested that the oxygen atom transfer from [MoOL] species to PPh to give [MoOL(bipy)] and from DMSO to [MoOL(bipy)] to yield [MoOL] is strongly favored, whereas the formation of ?-oxido dimer [MoOL], is much less probable.
Chemistry of oxidomolybdenum(IV) and -(VI) complexes with ONS donor ligands: Synthesis, computational evaluation and oxo-transfer reactions
Ugone Valeria;
2018
Abstract
A series of dioxidomolybdenum(VI) complexes, [MoOL] (1-6) and [MoOL(solv)] (1a-6a) {where solv (solvent) = DMSO (1a, 3a, 5a and 6a) and HO (2a and 4a)} have been synthesized using thiosemicarbazone ligands, HL. Furthermore, six monooxidomolybdenum(IV) complexes [MoOL(N-N)] (7-12) {where co-ligand (N-N) = 2,2?-bipyridine (bipy) (7, 10 and 11) and 1,10-phenanthroline (phen) (8, 9 and 12)} have also been synthesized from the corresponding Mo(VI) precursors, [MoOL] (1-6) by oxygen atom transfer (OAT) reaction. Complexes have been characterized by conventional methods, including X-ray crystallography, and DFT (density functional theory) calculations. OAT reactivity of Mo(VI) and Mo(IV) complexes have been successfully established through the formation of OPPh and MeS. These OAT products have been characterized by P NMR (OPPh), UV-Vis spectroscopy and GC-MS (MeS) and DFT simulations supported this finding through the prediction of ?G for the reaction of oxygen atom transfer. DFT methods suggested that the oxygen atom transfer from [MoOL] species to PPh to give [MoOL(bipy)] and from DMSO to [MoOL(bipy)] to yield [MoOL] is strongly favored, whereas the formation of ?-oxido dimer [MoOL], is much less probable.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.