Single crystals of the magnetic semiconductor CoIn0.5Cr1.5S4, belong to the system CoIn(2-2X)Cr(2X)S4 with x = 0.75, was grown by the chemical transport method. X-ray powder diffraction characterization by the Rietveld rnethod indicated that CoIn0.5Cr1.5S4 crystallizes in the space group Fd-3m, Z = 8, with a 10.0700(6) angstrom and V = 1021.2(1) angstrom(3), in a normal spinel structure. The temperature dependence of the DC magnetization suggests that the studied compound presents a ferromagnetic behavior with a Curie temperature Tc = 220 K. Sharp spin-glass like behavior was found also.

Structural characterization and magnetic properties of the spinel compound CoIn0.5Cr1.5S4

Bolzoni F
2008

Abstract

Single crystals of the magnetic semiconductor CoIn0.5Cr1.5S4, belong to the system CoIn(2-2X)Cr(2X)S4 with x = 0.75, was grown by the chemical transport method. X-ray powder diffraction characterization by the Rietveld rnethod indicated that CoIn0.5Cr1.5S4 crystallizes in the space group Fd-3m, Z = 8, with a 10.0700(6) angstrom and V = 1021.2(1) angstrom(3), in a normal spinel structure. The temperature dependence of the DC magnetization suggests that the studied compound presents a ferromagnetic behavior with a Curie temperature Tc = 220 K. Sharp spin-glass like behavior was found also.
2008
Istituto dei Materiali per l'Elettronica ed il Magnetismo - IMEM
75.50.Pp, 61.10.Nz
Semiconductor
spin-glass
X-ray powder diffraction
Rietveld refinement
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/20.500.14243/41041
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