The sigma-hole interaction represents a noncovalent interaction between atoms with sigma-hole(s)on their surface (such as halogens and chalcogens) and negative sites. Over the last decade, significantdevelopments have emerged in applications where the sigma-hole interaction was demonstrated to play akey role in the control over chirality. The aim of this review is to give a comprehensive overview of thecurrent advancements in the use of sigma-hole interactions in stereoselective processes, such as formationof chiral supramolecular assemblies, separation of enantiomers, enantioselective complexation andasymmetric catalysis.
Stereoselective Processes Based on sigma-Hole Interactions
Paola Peluso
;
2022
Abstract
The sigma-hole interaction represents a noncovalent interaction between atoms with sigma-hole(s)on their surface (such as halogens and chalcogens) and negative sites. Over the last decade, significantdevelopments have emerged in applications where the sigma-hole interaction was demonstrated to play akey role in the control over chirality. The aim of this review is to give a comprehensive overview of thecurrent advancements in the use of sigma-hole interactions in stereoselective processes, such as formationof chiral supramolecular assemblies, separation of enantiomers, enantioselective complexation andasymmetric catalysis.File | Dimensione | Formato | |
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2022_Molecules.pdf
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Descrizione: Stereoselective Processes Based on sigma-Hole Interactions
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