The catalytic methanation of CO via the strongly exothermic equilibrium Sabatier reaction requires the development of structured catalysts with enhanced mass- and heat-transfer features to limit hot-spot formation, avoid catalyst deactivation, and control process selectivity. In this work, we investigated the use of polymer-derived SiC open-cell foams as structured carriers onto which ?-AlO was applied by either dip-coating or pore-filling methods; eventually, Ru was dispersed by impregnation. The formation of an undesired insulating SiO layer on the surface of the SiC struts was prevented by a pyrolysis treatment under an inert atmosphere at temperatures varying from 800 up to 1800 °C. SiC foam substrates and their corresponding structured catalysts were characterized by SEM, XRD, N physisorption, and compressive strength measurements, and their CO methanation activity was tested at atmospheric pressure in a fixed bed flow reactor operated in the temperature range from 200 to 450 °C. SiC foams obtained at intermediate pyrolysis temperatures (1000-1200 °C) showed good mechanical strength and high compatibility with the Ru/AlO active catalytic overlayer.
Ru/Al2O3 on Polymer-Derived SiC Foams as Structured Catalysts for CO2 Methanation
Cepollaro EM;Cimino S;Lisi L;
2022
Abstract
The catalytic methanation of CO via the strongly exothermic equilibrium Sabatier reaction requires the development of structured catalysts with enhanced mass- and heat-transfer features to limit hot-spot formation, avoid catalyst deactivation, and control process selectivity. In this work, we investigated the use of polymer-derived SiC open-cell foams as structured carriers onto which ?-AlO was applied by either dip-coating or pore-filling methods; eventually, Ru was dispersed by impregnation. The formation of an undesired insulating SiO layer on the surface of the SiC struts was prevented by a pyrolysis treatment under an inert atmosphere at temperatures varying from 800 up to 1800 °C. SiC foam substrates and their corresponding structured catalysts were characterized by SEM, XRD, N physisorption, and compressive strength measurements, and their CO methanation activity was tested at atmospheric pressure in a fixed bed flow reactor operated in the temperature range from 200 to 450 °C. SiC foams obtained at intermediate pyrolysis temperatures (1000-1200 °C) showed good mechanical strength and high compatibility with the Ru/AlO active catalytic overlayer.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
