: Lithium titanium oxide (Li4Ti5O12, LTO) is an attractive negative electrode for the development of safe--next-generation--lithium-ion batteries (LIBs). LTO can find specific applications complementary to existing alternatives for LIBs thanks to its good rate capability at high C-rates, fast lithium intercalation, and high cycling stability. Furthermore, LIBs featuring LTO electrodes are inherently safer owing to the LTO's operating potential of 1.55 V vs. Li+/Li where the commonly used organic-based electrolytes are thermodynamically stable. Herein, we report the combined use of water-soluble sodium alginate (SA) binder and lithium bis(trifluoromethanesulfonyl)imide (Li FSI)-tetraglyme (1m-T) electrolyte and we demonstrate the improvement of the electrochemical performance of LTO-based electrodes with respect to those operating in conventional electrolyte 1 M LiPF6 -ethylene carbonate: dimethyl carbonate (LP30). We also tackle the analysis of the impact of combining the binder/electrolyte on the long-term cycling performance of LTO electrodes featuringSA or conventional polyvinylidene fluoride (PVdF) as binders. Therefore, to assess the impact of the combination of binder/electrolyte on performance, we performed post-mortem characterization by exsitu synchrotron diffraction experiments of LTO electrodes after cycling in LP30 and 1m-T electrolytes.
Deciphering the Interplay between Binders and Electrolytes on the Performance of Li4Ti5O12 Electrodes for Li-Ion Batteries
De Giorgio F;Brutti S;
2022
Abstract
: Lithium titanium oxide (Li4Ti5O12, LTO) is an attractive negative electrode for the development of safe--next-generation--lithium-ion batteries (LIBs). LTO can find specific applications complementary to existing alternatives for LIBs thanks to its good rate capability at high C-rates, fast lithium intercalation, and high cycling stability. Furthermore, LIBs featuring LTO electrodes are inherently safer owing to the LTO's operating potential of 1.55 V vs. Li+/Li where the commonly used organic-based electrolytes are thermodynamically stable. Herein, we report the combined use of water-soluble sodium alginate (SA) binder and lithium bis(trifluoromethanesulfonyl)imide (Li FSI)-tetraglyme (1m-T) electrolyte and we demonstrate the improvement of the electrochemical performance of LTO-based electrodes with respect to those operating in conventional electrolyte 1 M LiPF6 -ethylene carbonate: dimethyl carbonate (LP30). We also tackle the analysis of the impact of combining the binder/electrolyte on the long-term cycling performance of LTO electrodes featuringSA or conventional polyvinylidene fluoride (PVdF) as binders. Therefore, to assess the impact of the combination of binder/electrolyte on performance, we performed post-mortem characterization by exsitu synchrotron diffraction experiments of LTO electrodes after cycling in LP30 and 1m-T electrolytes.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.