In this work, a Lagrangian particle model able to account for simple chemical reactions between NO and O-3 has been improved to consider the photolysis of NO2. A system of chemical equations is numerically solved on a Eulerian grid, while the particle trajectories are moved in a Lagrangian frame. The NOx emissions of a power plant in real atmosphere, situated in a complex topography environment, have been considered as a test case. The simulated episodes refer to the diurnal time, when the ultraviolet radiation activates the NO2. Comparisons between NO/NO2's concentrations ratio are presented in terms of scatter plots and statistical indexes analysis.

A Lagrangian particle model with chemical reactions: application in real atmosphere

Ferrero Enrico
2011

Abstract

In this work, a Lagrangian particle model able to account for simple chemical reactions between NO and O-3 has been improved to consider the photolysis of NO2. A system of chemical equations is numerically solved on a Eulerian grid, while the particle trajectories are moved in a Lagrangian frame. The NOx emissions of a power plant in real atmosphere, situated in a complex topography environment, have been considered as a test case. The simulated episodes refer to the diurnal time, when the ultraviolet radiation activates the NO2. Comparisons between NO/NO2's concentrations ratio are presented in terms of scatter plots and statistical indexes analysis.
2011
atmospheric dispersion
NO
chemistry model
Lagrangian particle model
photo-stationary equilibrium
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/20.500.14243/420534
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