Cellulose acetate (CA) is an attractive membrane polymer for CO2 capture market. However, its low CO2 permeability hampers its application as part of a membrane for most relevant types of CO2 containing feeds. This work investigates the enhancement of CA separation performance by incorporating ionic liquid-like pendants (1-methylimidazol, 1-methylpyrrolidine, and 2-hydroxyethyldimethylamine (HEDMA) on the CA backbone. These CA-based polyelectrolytes (PEs), synthesised by covalent grafting of cationic pendants with anion metathesis, were characterised by NMR, FTIR, DSC/TGA, and processed into thin-film composite membranes. The membrane performance in CO2/N2 mixed-gas permeation experiments shows a decrease in CO2 and N2 permeability and an initial decrease and then gradual increase in CO2/N2 selectivity with increasing HEDMA content. The amount of HEDMA attached to the CA backbone determines overall separation process in bifunctional PEs. This indicates that the hydroxy-substituted cationic pendants alter interactions between PEs network and permeating CO2 molecules, suggesting possibilities for further improvements.
Influence of ionic liquid-like cationic pendants composition in cellulose based polyelectrolytes on membrane-based CO2 separation
Jansen Johannes C;
2021
Abstract
Cellulose acetate (CA) is an attractive membrane polymer for CO2 capture market. However, its low CO2 permeability hampers its application as part of a membrane for most relevant types of CO2 containing feeds. This work investigates the enhancement of CA separation performance by incorporating ionic liquid-like pendants (1-methylimidazol, 1-methylpyrrolidine, and 2-hydroxyethyldimethylamine (HEDMA) on the CA backbone. These CA-based polyelectrolytes (PEs), synthesised by covalent grafting of cationic pendants with anion metathesis, were characterised by NMR, FTIR, DSC/TGA, and processed into thin-film composite membranes. The membrane performance in CO2/N2 mixed-gas permeation experiments shows a decrease in CO2 and N2 permeability and an initial decrease and then gradual increase in CO2/N2 selectivity with increasing HEDMA content. The amount of HEDMA attached to the CA backbone determines overall separation process in bifunctional PEs. This indicates that the hydroxy-substituted cationic pendants alter interactions between PEs network and permeating CO2 molecules, suggesting possibilities for further improvements.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
