Clay minerals at the paleocene-eocene thermal maximum: Interpretations, limits, and perspectives

The Paleocene-Eocene Thermal Maximum (PETM) was an "extreme" episode of environmental stress that affected the Earth in the past, and it has numerous affinities concerning the rapid increase in the greenhouse effect. It has left several biological, compositional, and sedimentary facies footprints in sedimentary records. Clay minerals are frequently used to decipher environmental effects because they represent their source areas, essentially in terms of climatic conditions and of transport mechanisms (a more or less fast travel, from the bedrocks to the final site of recovery). Clay mineral variations at the PETM have been studied by several authors in terms of climatic and provenance indicators, but also as tracers of more complicated interplay among different factors requiring integrated interpretation (facies sorting, marine circulation, wind transport, early diagenesis, etc.). Clay minerals were also believed to play a role in the recovery of pre-episode climatic conditions after the PETM exordium, by becoming a sink of atmospheric CO2 that is considered a necessary steep to switch off the greenhouse hyperthermal effect. This review aims to consider the use of clay minerals made by different authors to study the effects of the PETM and their possible role as effective (simple) proxy tools for environmental reconstructions.