Aqueous glycerol was used as the hydrogen source for the reduction of CO2 to the hydrogen carrier formic acid in the presence of the catalyst [RuCl2(PPh3)3]. All intermediates were identified and characterized. Glycerol was converted into glycolic acid, HO?CH2?COOH, that was identified by using 1H and 13C NMR spectroscopy.
RuII-mediated hydrogen transfer from aqueous glycerol to CO 2 : From waste to value-added products
2011
Abstract
Aqueous glycerol was used as the hydrogen source for the reduction of CO2 to the hydrogen carrier formic acid in the presence of the catalyst [RuCl2(PPh3)3]. All intermediates were identified and characterized. Glycerol was converted into glycolic acid, HO?CH2?COOH, that was identified by using 1H and 13C NMR spectroscopy.File in questo prodotto:
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