An unusual diacylglycerol, archidorin [1], has been isolated from the mantle of the mollusk Archidoris tuberculata. Glycerol is esterified with tiglic acid and with a diterpenoid clerodane acid at positions 1-sn and 2-sn, respectively. Absolute stereochemistry of the glycerol residue is assigned by chemical correlation with 1,2-O-isopropylidene-sn-glycerol.
ARCHIDORIN: A NEW ICHTHYOTOXIC DIACYLGLYCEROL FROM THE ATLANTIC DORID NUDIBRANCH ARCHIDORIS TUBERCULATA
CIMINO G;
1993
Abstract
An unusual diacylglycerol, archidorin [1], has been isolated from the mantle of the mollusk Archidoris tuberculata. Glycerol is esterified with tiglic acid and with a diterpenoid clerodane acid at positions 1-sn and 2-sn, respectively. Absolute stereochemistry of the glycerol residue is assigned by chemical correlation with 1,2-O-isopropylidene-sn-glycerol.File in questo prodotto:
Non ci sono file associati a questo prodotto.
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
