A novel chiral tridentate phosphine ligand based on ferrocene (5) can be readily obtained from cyclohexylphosphine and N,N-dimethyl-(S)-l-[(R)-2- (diphenylphosphino)ferrocenyllethylamine (4) in acetic acid. Ligand 5 adopts a meridional coordination geometry with d8-metal centers. The crystal structure of [Pd(5)ClIPF6 (6) has been determined.
A New Chiral Tridentate Ferrocenyl Ligand. Synthesis and Characterization of Its Palladium(I1) and Nickel(I1) Complexes
Barbaro Pierluigi;
1995
Abstract
A novel chiral tridentate phosphine ligand based on ferrocene (5) can be readily obtained from cyclohexylphosphine and N,N-dimethyl-(S)-l-[(R)-2- (diphenylphosphino)ferrocenyllethylamine (4) in acetic acid. Ligand 5 adopts a meridional coordination geometry with d8-metal centers. The crystal structure of [Pd(5)ClIPF6 (6) has been determined.File in questo prodotto:
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