The acetone sensing mechanism by WO 3 was investigated through a combined experimental and theoret- ical approach. The ?-monoclinic WO 3 powder was synthesized by a template-mediated sol-gel method and characterized on structural, surface, morphological and optical points of view. A thin film of WO 3 was deposited on interdigitated Au electrodes by hot-spray method and tested at 300 oC (while apply- ing a bias of 1.0 V) for acetone gas sensing, both in presence and absence of oxygen in the gas carrier. Interestingly, the absence of oxygen had no significant effect on the sensor response intensity but it dra- matically increased the recovery times (from 120 s to 2700 s). In order to explain these experimental results, by means of ab initio density functional theory calculations, we modeled a defective ?-WO 3 surface structure and simulated the adsorption of acetone and oxygen molecules on top of it. We un- precedentedly evidenced that, in presence of surface oxygen vacancies, both acetone adsorption and its oxidation reaction can occur. However, their contribution to the sensor response strictly depends on the inert/oxidative atmosphere present in the sensing chamber, which in turn strongly affects the surface oxygen population. Our findings can either be the guidelines for future studies aimed at delineating the possible reaction products or pave the way for the engineering of tailored nanomaterials having specific surface features and enhanced sensing properties.
Unveiling the acetone sensing mechanism by WO3 chemiresistors through a joint theory-experiment approach
Raffaella Soave;Fausto Cargnoni;Mario Italo Trioni;
2021
Abstract
The acetone sensing mechanism by WO 3 was investigated through a combined experimental and theoret- ical approach. The ?-monoclinic WO 3 powder was synthesized by a template-mediated sol-gel method and characterized on structural, surface, morphological and optical points of view. A thin film of WO 3 was deposited on interdigitated Au electrodes by hot-spray method and tested at 300 oC (while apply- ing a bias of 1.0 V) for acetone gas sensing, both in presence and absence of oxygen in the gas carrier. Interestingly, the absence of oxygen had no significant effect on the sensor response intensity but it dra- matically increased the recovery times (from 120 s to 2700 s). In order to explain these experimental results, by means of ab initio density functional theory calculations, we modeled a defective ?-WO 3 surface structure and simulated the adsorption of acetone and oxygen molecules on top of it. We un- precedentedly evidenced that, in presence of surface oxygen vacancies, both acetone adsorption and its oxidation reaction can occur. However, their contribution to the sensor response strictly depends on the inert/oxidative atmosphere present in the sensing chamber, which in turn strongly affects the surface oxygen population. Our findings can either be the guidelines for future studies aimed at delineating the possible reaction products or pave the way for the engineering of tailored nanomaterials having specific surface features and enhanced sensing properties.File | Dimensione | Formato | |
---|---|---|---|
prod_443883-doc_199935.pdf
accesso aperto
Descrizione: Unveiling the acetone sensing mechanism by WO3 chemiresistors through a joint theory-experiment approach
Tipologia:
Versione Editoriale (PDF)
Dimensione
2.82 MB
Formato
Adobe PDF
|
2.82 MB | Adobe PDF | Visualizza/Apri |
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.