The present work aims in discussing a principle that distinguishes between elastic parameters sets ( Ko, K', Vo,...), on the basis of an energetic criterion: once a reference set is given, another one can be fixed (minimum), so that they are as close as possible to each other, but yield non-equivalent deformation energy curves, deltaGdeform. Delta G deform calculated using the equation of state (EoS), and its uncertainty, sigma [delta Gdeform], obtained by a propagation of the errors affecting parameters set are crucial to fix which mineral assemblage forms at P-T conditions and allow one to assess the reliability of such a prediction. We explore some properties related to the principle introduced, using the average values of the elastic parameters found in literature and related uncertainties for di-octahedral mica, olivine, garnet and clinopyroxene. Two elementary applications are briefly discussed: the effect of refining V0 in fitting EoSs to P-V experimental data, in the case of garnet and omphacite, and the phengite 3T-2M1 relative stability, controlled by pressure.

The notion of "distinguishibility" between bulk elastic parameters on the basis of the Gibbs energy deformation energy.

Pavese A;Diella V
2010

Abstract

The present work aims in discussing a principle that distinguishes between elastic parameters sets ( Ko, K', Vo,...), on the basis of an energetic criterion: once a reference set is given, another one can be fixed (minimum), so that they are as close as possible to each other, but yield non-equivalent deformation energy curves, deltaGdeform. Delta G deform calculated using the equation of state (EoS), and its uncertainty, sigma [delta Gdeform], obtained by a propagation of the errors affecting parameters set are crucial to fix which mineral assemblage forms at P-T conditions and allow one to assess the reliability of such a prediction. We explore some properties related to the principle introduced, using the average values of the elastic parameters found in literature and related uncertainties for di-octahedral mica, olivine, garnet and clinopyroxene. Two elementary applications are briefly discussed: the effect of refining V0 in fitting EoSs to P-V experimental data, in the case of garnet and omphacite, and the phengite 3T-2M1 relative stability, controlled by pressure.
2010
Istituto per la Dinamica dei Processi Ambientali - IDPA - Sede Venezia
Istituto di Geologia Ambientale e Geoingegneria - IGAG
Elastic parameters
Deformation energy
Uncertainty
Phase stability
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/20.500.14243/433576
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