Chromate reduction to trivalent chromium was investigated via X-ray Absorption Spectroscopy (XAS). To demonstrate the influence of the cytochrome protein (cyt c) on the reduction, we recovered Extended X-ray Absorption Fine Structure (EXAFS) spectra, varying the pH of the mixture containing the reduced cytochrome c (cyt c) protein and the chromate.

The photosynthetic purple non-sulphur bacterium Rhodobacter (R.) sphaeroides has been proposed as main actor in several bioremediation processes given its highly versatile metabolism. As previously showed, R. sphaeroides can grow photosynthetically in presence of chromate, a well know and dangerous water-soluble pollutant. The main strategy employed by the bacterium for chromate pollution abatement is its reduction to the less toxic Cr3+ form.

The role of cytochrome c in the chromate reduction by Rhodobacter sphaeroides.

-
2022

Abstract

The photosynthetic purple non-sulphur bacterium Rhodobacter (R.) sphaeroides has been proposed as main actor in several bioremediation processes given its highly versatile metabolism. As previously showed, R. sphaeroides can grow photosynthetically in presence of chromate, a well know and dangerous water-soluble pollutant. The main strategy employed by the bacterium for chromate pollution abatement is its reduction to the less toxic Cr3+ form.
2022
Inglese
2022 IEEE International Workshop on Metrology for the Sea; Learning to Measure Sea Health Parameters (MetroSea)
96
100
5
978-1-6654-9942-2
IEEE
New York
STATI UNITI D'AMERICA
Sì, ma tipo non specificato
3/5/2022 - 5/10/2022
Milazzo, Italy
Chromate reduction to trivalent chromium was investigated via X-ray Absorption Spectroscopy (XAS). To demonstrate the influence of the cytochrome protein (cyt c) on the reduction, we recovered Extended X-ray Absorption Fine Structure (EXAFS) spectra, varying the pH of the mixture containing the reduced cytochrome c (cyt c) protein and the chromate.
chromate
chromate reductase
cytochrome c
Rhodobacter sphaeroides
EXAFS
0
none
273
info:eu-repo/semantics/conferenceObject
04 Contributo in convegno::04.01 Contributo in Atti di convegno
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/20.500.14243/434709
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