An imine-linked (+)-syn-benzotricamphor derivative gives access to chiral unimolecular cages exhibiting internal cavities of new shapes and volumes. One of these hosts hydrocarbon gases at low temperatures in solution through CH-pi attractive interactions. No encapsulation is observed when the cage structure is too narrow or too large for the guest.
Gases as Guests in Benzocyclotrimer Cage Hosts
Tartaggia Stefano;
2009
Abstract
An imine-linked (+)-syn-benzotricamphor derivative gives access to chiral unimolecular cages exhibiting internal cavities of new shapes and volumes. One of these hosts hydrocarbon gases at low temperatures in solution through CH-pi attractive interactions. No encapsulation is observed when the cage structure is too narrow or too large for the guest.File in questo prodotto:
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