To better understand the batch production of 5-nitrosalicylic acid by means of the nitration of salicylic acid through the mixture nitric acid/acetic acid, the solubility of the two main mononitro derivatives of salicylic acid is investigated. For this purpose, the behavior of the two mononitro compounds in the ternary system organic/ acetic acid/nitric acid is separately studied at different temperatures (288 to 303) K and nitric acid concentrations [(0 to 2) molâL-1 for 5-nitrosalicylic acid, (0 to 1) molâL-1 for 3-nitrosalicylic acid]. The solubility of these compounds increases with a rise in temperature, whereas only the solubility of 5-nitrosalicylic acid is dependent upon the nitric acid concentration. The mutual effect of each organic acid on the solubility of the other is also investigated. The observed dependencies are explained through simple thermodynamic relationships.
Solubility of 5-nitro- and 3-nitrosalicylic acids in an acetic acid/nitric acid mixture
Sanchirico R
2007
Abstract
To better understand the batch production of 5-nitrosalicylic acid by means of the nitration of salicylic acid through the mixture nitric acid/acetic acid, the solubility of the two main mononitro derivatives of salicylic acid is investigated. For this purpose, the behavior of the two mononitro compounds in the ternary system organic/ acetic acid/nitric acid is separately studied at different temperatures (288 to 303) K and nitric acid concentrations [(0 to 2) molâL-1 for 5-nitrosalicylic acid, (0 to 1) molâL-1 for 3-nitrosalicylic acid]. The solubility of these compounds increases with a rise in temperature, whereas only the solubility of 5-nitrosalicylic acid is dependent upon the nitric acid concentration. The mutual effect of each organic acid on the solubility of the other is also investigated. The observed dependencies are explained through simple thermodynamic relationships.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
