Hydrogen production via water electrolysis is considered the "greenest" way because it does not produce any direct carbon emissions when powered by renewable sources. Among the different technologies of electrolyzers, increasing interest is registered by that one based on anion-exchange membranes (AEMs). In this work, a FAA3-50 anion-exchange membrane (from FuMa-Tech) is used, after the KOH solution (1 M) exchange, as electrolyte/separator in an electrolysis cell of 5 cm geometrical area. Commercial IrO and 40% Pt/C catalysts are used at the anode and cathode, respectively, to evaluate the membrane under the most convenient conditions. The influence of cell temperature, membrane-electrode assembly (MEA) procedure (catalyst-coated membrane or catalyst coated electrode), and pure water or KOH solution on electrolyzer performance are analyzed. It appears that the catalyst-coated membrane approach, using the FAA3-50 membrane, allows higher temperature operation. However, diluted KOH solution is necessary to increase the membrane conductivity and the cell performance.
Optimal operating conditions evaluation of an anion-exchange-membrane electrolyzer based on FUMASEP® FAA3-50 membrane
Gatto I;Lo Vecchio C;Zignani S;Patti A;Baglio V
2023
Abstract
Hydrogen production via water electrolysis is considered the "greenest" way because it does not produce any direct carbon emissions when powered by renewable sources. Among the different technologies of electrolyzers, increasing interest is registered by that one based on anion-exchange membranes (AEMs). In this work, a FAA3-50 anion-exchange membrane (from FuMa-Tech) is used, after the KOH solution (1 M) exchange, as electrolyte/separator in an electrolysis cell of 5 cm geometrical area. Commercial IrO and 40% Pt/C catalysts are used at the anode and cathode, respectively, to evaluate the membrane under the most convenient conditions. The influence of cell temperature, membrane-electrode assembly (MEA) procedure (catalyst-coated membrane or catalyst coated electrode), and pure water or KOH solution on electrolyzer performance are analyzed. It appears that the catalyst-coated membrane approach, using the FAA3-50 membrane, allows higher temperature operation. However, diluted KOH solution is necessary to increase the membrane conductivity and the cell performance.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
