Citronella oil from Cymbopogon winterianus is widely produced in Indonesia (Java type). A way to increase the value of this product is to transform citronellal contained in the oil into menthol, one of the most sought after fragrance products. The one pot citronellal to menthol transformation is also a war horse of tandem reactions over heterogeneous catalysts. Here we wish to report our results in the one pot transformation of citronellal into menthol over a Ni/Al2O3 catalyst. While alumina showed to be a poor catalyst for the transformation of citronellal into isopulegol, ZnBr2 modified alumina allowed to obtain very fast formation of isopulegol. However, when Ni was supported on the modified alumina and used under hydrogenation conditions only isopulegol was obtained even after long reaction times. On the contrary a 10% Ni/ Al2O3 catalyst showed fairly good activity. These results can be ascribed to very big differences in Ni particle size and to reduced surface area of the Zn containing catalyst.

One pot transformation of citronellal to menthol over Ni/gamma-Al2O3

Psaro R;Santoro F;Sordelli L
2011

Abstract

Citronella oil from Cymbopogon winterianus is widely produced in Indonesia (Java type). A way to increase the value of this product is to transform citronellal contained in the oil into menthol, one of the most sought after fragrance products. The one pot citronellal to menthol transformation is also a war horse of tandem reactions over heterogeneous catalysts. Here we wish to report our results in the one pot transformation of citronellal into menthol over a Ni/Al2O3 catalyst. While alumina showed to be a poor catalyst for the transformation of citronellal into isopulegol, ZnBr2 modified alumina allowed to obtain very fast formation of isopulegol. However, when Ni was supported on the modified alumina and used under hydrogenation conditions only isopulegol was obtained even after long reaction times. On the contrary a 10% Ni/ Al2O3 catalyst showed fairly good activity. These results can be ascribed to very big differences in Ni particle size and to reduced surface area of the Zn containing catalyst.
2011
Istituto di Scienze e Tecnologie Molecolari - ISTM - Sede Milano
citronellal
isopulegol
menthol
domino reactions
bifunctional catalysts
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/20.500.14243/439330
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