How hydrocarbons move along faults: Evidence from microstructural observations of hydrocarbon-bearing carbonate fault rocks

The microscale mechanisms of hydrocarbons movement along faults and fault zones, the potential carriers of hydrocarbons toward the productive geological traps, remain largely unknown. The majority of previous studies inferred the hydraulic behavior of faults with respect to hydrocarbon movements without providing meso and microstructural observations from faults permeated by hydrocarbons. To fill this gap, we document meso-structures together with the first fossil microstructural portraits of hydrocarbon flow and pathways along two hydrocarbon-bearing carbonate-hosted normal faults exposed in the central Apennines, Italy. In particular, we show that hydrocarbons cyclically move within tectonically active carbonate normal faults possibly during interseismic and coseismic phases of the seismic cycle. Channelized structures, injection features, and clast-cortex grains suggest the occurrence of transient and localized pulses of pressurized hydrocarbons during coseismic slip. In particular, clast-cortex grains are very similar to microstructures that develop along fault planes for slip velocities between 0.0001 and 1 m/s. Patches of hydrocarbon-bearing breccias/cataclasites with lobate and irregular boundaries, crackle breccias filled by hydrocarbons, and hydrocarbons arrested against hydrocarbon-free discrete fault planes suggest hydrocarbon flow during the interseismic phases with hydrocarbon (over)pressure dissipation after coseismic phases. Fault permeability is created during the coseismic phase and hydrocarbons penetrate the most permeable and uncemented uncohesive fault rocks within the damage zone and arrest against and/or within low-permeability and cemented fault cores. Results are consistent with previous numerical simulations on hydrocarbon movements along faults and time-lapse periods within tectonically active faults and along permeable zones cyclically created by seismic activity. Results from this paper are crucial for modelling the hydraulic behavior of carbonate fault damage zone, which have progressively gained popularity as targets of hydrocarbon exploration and production and for CO2 or H storage.