Anomalous statistical distributions that exhibit asymptotic behavior different from the exponential Boltzmann-Gibbs tail are typical of complex systems constrained by long-range interactions or time-persistent memory effects at the stationary non-equilibrium or meta-equilibrium. In this framework, a nonlinear Smoluchowski equation, which models the system's time evolution towards its steady state, is obtained using the gradient flow method based on a free-energy potential related to a given generalized entropic form. Comparison of the stationary distribution resulting from the maximization of entropy for a canonical ensemble with the steady state distribution resulting from the Smoluchowski equation gives an Einstein-Smoluchowski-like relation. Despite this relationship between the mobility of particle ? and the diffusion coefficient D retains its original expression: ? = ? D, appropriate considerations, physically motivated, force us an interpretation of the parameter ? different from the traditional meaning of inverse temperature.

On the Einstein-Smoluchowski relation in the framework of generalized statistical mechanics

LR Evangelista;G Barbero;AM Scarfone
2024

Abstract

Anomalous statistical distributions that exhibit asymptotic behavior different from the exponential Boltzmann-Gibbs tail are typical of complex systems constrained by long-range interactions or time-persistent memory effects at the stationary non-equilibrium or meta-equilibrium. In this framework, a nonlinear Smoluchowski equation, which models the system's time evolution towards its steady state, is obtained using the gradient flow method based on a free-energy potential related to a given generalized entropic form. Comparison of the stationary distribution resulting from the maximization of entropy for a canonical ensemble with the steady state distribution resulting from the Smoluchowski equation gives an Einstein-Smoluchowski-like relation. Despite this relationship between the mobility of particle ? and the diffusion coefficient D retains its original expression: ? = ? D, appropriate considerations, physically motivated, force us an interpretation of the parameter ? different from the traditional meaning of inverse temperature.
2024
Istituto dei Sistemi Complessi - ISC
Einstein-Smoluchowski relation
Maximal entropy principle
Zeroth principle of thermodynamics
Physical temperature
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/20.500.14243/450446
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