The melt viscosity (h) of anhydrous and hydrous peridotite was investigated using a multipronged approach combining micropenetration viscometry, conventional DSC, flash DSC and Brillouin spectroscopy. Raman spectroscopy measurements were used to verify the absence of crystallization and/or degassing during high-temperature measurements of these extremely reactive glasses and melts, ensuring that the data corresponded to the crystal-free melt viscosity. Based on the experimental data, an accurate description of the viscosity of peridotite melts over thirteen orders of magnitude (from Tg to ????10-1?Pa?s) is provided in a broad range of compositions and oxidation states. Since empirical models predict viscosities that can significantly deviate from measured data to varying degrees, a new model was developed for the temperature- and H2O-dependent viscosity of peridotite melts (up to 12?mol% H2O content).

Viscosity of anhydrous and hydrous peridotite melts

Danilo Di Genova
Primo
Conceptualization
;
2023

Abstract

The melt viscosity (h) of anhydrous and hydrous peridotite was investigated using a multipronged approach combining micropenetration viscometry, conventional DSC, flash DSC and Brillouin spectroscopy. Raman spectroscopy measurements were used to verify the absence of crystallization and/or degassing during high-temperature measurements of these extremely reactive glasses and melts, ensuring that the data corresponded to the crystal-free melt viscosity. Based on the experimental data, an accurate description of the viscosity of peridotite melts over thirteen orders of magnitude (from Tg to ????10-1?Pa?s) is provided in a broad range of compositions and oxidation states. Since empirical models predict viscosities that can significantly deviate from measured data to varying degrees, a new model was developed for the temperature- and H2O-dependent viscosity of peridotite melts (up to 12?mol% H2O content).
2023
Istituto di Scienza, Tecnologia e Sostenibilità per lo Sviluppo dei Materiali Ceramici - ISSMC (ex ISTEC)
Peridotite melt
Viscosity
Glass transition
Calorimetry
Brillouin spectroscopy
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/20.500.14243/451329
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