Menthyl (S)-p-bromobenzenesulfinate was prepared and subjected to two different substitution reactions with Grignard reagents. Enantiopure dialkyl sulfoxides were quickly obtained with this conceptually straightforward and experimentally simple procedure.
Highly Stereoselective Route to Dialkyl Sulfoxides Based upon the Sequential Displacement of Oxygen and Carbon Leaving Groups by Grignard Reagents on Sulfinyl Compoundss
Cardellicchio C;
2001
Abstract
Menthyl (S)-p-bromobenzenesulfinate was prepared and subjected to two different substitution reactions with Grignard reagents. Enantiopure dialkyl sulfoxides were quickly obtained with this conceptually straightforward and experimentally simple procedure.File in questo prodotto:
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