The relative ratio of the dimers obtained by laccase-catalyzed oxidation of tetrahydronaphthyl derivatives was profoundly influenced by the nature of the organic solvent used. For instance, in the oxidation of 5,6,7,8-tetrahydronaphtalen-2-ol (1), the formation of the symmetrical 1,1'-product la with respect to the 1,3' dimer 1b was highly favored in the aromatic solvents benzene and toluene.
Significant and unexpected solvent influence on the selectivity of laccase-catalyzed coupling of tetrahydro-2-naphthol derivatives
Riva S;
2005
Abstract
The relative ratio of the dimers obtained by laccase-catalyzed oxidation of tetrahydronaphthyl derivatives was profoundly influenced by the nature of the organic solvent used. For instance, in the oxidation of 5,6,7,8-tetrahydronaphtalen-2-ol (1), the formation of the symmetrical 1,1'-product la with respect to the 1,3' dimer 1b was highly favored in the aromatic solvents benzene and toluene.File in questo prodotto:
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