Reconstructing redox variations in a young, expanding ocean basin (Cretaceous Central Atlantic)

The redox sensitive elements (RSE) are indicators of organic matter (OM)-rich rocks and provide valuable information on paleoenvironmental parameters, including organic productivity, chemical evolution of water masses, ocean residence times and sea-bottom redox conditions. Yet, their potential to understand global environmental changes is hindered by the scarcity of continuous geological records, often highly fragmented in space and time. In this contribution, a large dataset from five closely spaced sedimentary sections in the Western African margin is used to reconstruct a 40 myr-long record of the redox conditions in a time spanning from the early Aptian to early-middle Campanian. Studied intervals were originally located in different positions of the embryonic Atlantic Ocean, and intercept four separated oceanic anoxic events (OAE1c, OAE1d, OAE2 and OAE3). The complete geochemical characterization revealed the changes of Mn, V, Ni, Cu, Zn, Mo, U and Se during the deposition of OM-rich sediments, as a function of their depositional environments, redox conditions, and time. It is shown that, although enrichments of RSE are triggered by increasingly reducing seafloor conditions, the extent to which these elements are retained within the sedimentary record depend on both local variations in detrital inputs and global perturbations of the marine RSE inventories. The analyses show that RSE are characteristically enriched with respect to global shale values, having geochemical characteristics (i.e., high Mo/TOC and high Mo/U) suggestive of suboxic to sulfidic conditions from the late Albian to Campanian.