The interaction of the metastable core-hole state of the water molecule with the continua corresponding to the Auger decay channels has been evaluated in order to derive an energy contribution to the core-hole ionization potential not included in standard variational calculations. The value obtained (0.06 eV) is smaller than the relativistic and vibronic corrections but it is not negligible, considering the experimental accuracy.
DISCRETE-CONTINUUM INTERACTION FOR THE CORE-HOLE STATE OF WATER
CARRAVETTA V;
1988
Abstract
The interaction of the metastable core-hole state of the water molecule with the continua corresponding to the Auger decay channels has been evaluated in order to derive an energy contribution to the core-hole ionization potential not included in standard variational calculations. The value obtained (0.06 eV) is smaller than the relativistic and vibronic corrections but it is not negligible, considering the experimental accuracy.File in questo prodotto:
Non ci sono file associati a questo prodotto.
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
